Total syntheses of (+)- and (−)-Crinane via Pd(0)-Catalyzed deacylative allylation
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DOI: 10.1016/j.tet.2021.131928
Abstract: Abstract An efficient Pd(0)-catalyzed deacylative allylation (DaA) of enolcarbonates (pro-nucleophile) prepared from 2-arylcyclohexanones sharing acyl functionality at C2-position with readily available allylic alcohols (pro-electrophiles) by employing Pd(0)-catalysis under mild reaction conditions. The methodology can be… read more here.
Keywords: syntheses crinane; methodology; catalyzed deacylative; total syntheses ... See more keywords