Divergent total syntheses of five illudalane sesquiterpenes and assignment of the absolute configuration.
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DOI: 10.1039/c9cc00933g
Abstract: Concise, divergent total syntheses of five bioactive illudalane sesquiterpenes have been achieved. Our synthesis features an intermolecular [2+2+2] cycloaddition, and a lactone-directed aromatic C-H oxygenation to generate a temporary phenolic hydroxyl group which enables regioselective… read more here.
Keywords: total syntheses; syntheses five; divergent total; illudalane sesquiterpenes ... See more keywords