Syntheses and investigation of metal complexes with macrocyclic polythioether ligands.
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DOI: 10.1039/d1fd00062d
Abstract: Copper(I) complexes with the macrocyclic thioether ligands 1,4,8,11-tetrathiacyclotetradecane (tetrathiacyclam, 14-S4) and 1,8-dithia-4,11-diazacyclotetradecane (dithiacyclam, 14-N2S2) were synthesised and structurally characterised. While the copper(I) complexes showed no reactivity towards dioxygen, the formation of "dioxygen adduct complexes" could… read more here.
Keywords: syntheses investigation; dioxygen; metal complexes; investigation metal ... See more keywords