Syntheses and reactivity of oxorhenium(V) complexes containing tetraphenylimidodiphosphinato and dialkyldithiocarbamato ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119234
Abstract: Abstract Treatment of [ReOCl2{N(Ph2PO)2}(PPh3)] with one equivalent of sodium dialkyldithiocarbamate R2NCS2Na (R = Me, Et, iPr) in a mixed solvent of chloroform and methanol afforded the corresponding oxorhenium(V) complexes [ReOCl{N(Ph2PO)2}(S2CNMe2)]·CH2Cl2 (1), [ReOCl{N(Ph2PO)2}(S2CNEt2)] (2) and [ReOCl{N(Ph2PO)2}(S2CNiPr2)] (3). Reactions… read more here.
Keywords: complexes containing; syntheses reactivity; reactivity oxorhenium; oxorhenium ... See more keywords