Syntheses, Structures and Luminescence Sensing Properties of Two Cd(II) MOFs Constructed from Mixed Ligands
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DOI: 10.1007/s10876-020-01931-3
Abstract: Hydrothermally reaction of Cd(NO 3 ) 2 ·4H 2 O, pimelic acid (H 2 Pim) mixed with two N-containing ligands of 1,2-bis(2-methyl-imidazol-1-ylmethyl)benzene (1,2-mbix) or 1,3-bis(2-methyl-imidazol-1-ylmethyl)benzene (1,3-mbix) gave rise to two new Cd(II) MOFs, [Cd(Pim)(1,2-mbix)] (… read more here.
Keywords: luminescence sensing; structures luminescence; syntheses structures; properties two ... See more keywords
Hydrothermal syntheses and structures of cobalt(II) and copper(II) coordination polymers with 1-tetrazole-phenyl-4-methylphosphonate ligands
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DOI: 10.1016/j.ica.2016.12.015
Abstract: Abstract Hydrothermal reactions of copper(II) and cobalt(II) salts with 1-tetrazole-phenyl-4-methylphosphonic acid yielded the coordination polymers [Cu(H 2 O)(HO 3 PCH 2 C 6 H 4 CN 4 )]·H 2 O ( 1 ·H 2 O)… read more here.
Keywords: structures cobalt; syntheses structures; tetrazole phenyl; coordination polymers ... See more keywords
Syntheses, structures and catalytic activities of two cyclopalladated complexes derived from N'-(2-naphthylidene)benzohydrazide
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DOI: 10.1016/j.jorganchem.2017.08.002
Abstract: Abstract Condensation reaction of 2-naphthaldehyde with one equivalent of benzohydrazide in presence of acetic acid in refluxing methanol yielded the Schiff base N' -(2-naphthylidene)benzohydrazide (H 2 L) in 86% yield. Reaction of equimolar amounts of… read more here.
Keywords: structures catalytic; benzohydrazide; syntheses structures; activities two ... See more keywords
Syntheses, structures and luminescent properties of two novel Zn (II) coordination polymers
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DOI: 10.1016/j.jssc.2017.12.028
Abstract: Abstract Two new coordination polymers, namely [Zn(TZMB)]n (1) and {[Zn(TZMB)](H2TZMB)]·(C2H5OH)0.5(H2O)2.5}n (2), (H2TZMB = 4,4′-(1H-1,2,4-triazol-1-yl)methylene-bis(benzonic acid), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis (EA), IR spectrum analysis (IR),… read more here.
Keywords: ray diffraction; analysis; luminescent properties; syntheses structures ... See more keywords
Solvothermal syntheses, structures and fluorescent properties of six ZnII/CdII coordination polymers constructed from N-donor ligands and multidentate organic acid
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DOI: 10.1016/j.jssc.2018.11.039
Abstract: Abstract Six new coordination polymers(CPs) {[Cd(L1)(CHDA)]·H2O}n (1), [Zn3(L1)2(1,2,4-BTC)2(H2O)4]n (2), [Zn(L2)(D-CAM)(H2O)]n (3), [Zn3(L2)(1,2,4-BTC)2(H2O)4]n (4), [Cd(L2)(1,3,5-HBTC)]n (5) and {[Zn(L2)(4,4´-BOA)]·H2O}n (6) (L1 = 3,6-bis(imidazol-1-yl)pyridazine, L2 = 3,6-bis(benzimidazol-1-yl)pyridazine, 1,4-H2CHDA = (1 S,4 S)-cyclohexane-1,4-dicarboxylic acid, 1,2,4-H3BTC = benzene-1,2,4-tricarboxylic acid, D-CAM = (1 R,3 S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid, 1,3,5-H3BTC = benzene-1,3,5-tricarboxylic acid, 4,4´-H2OBA = 4,4´-oxydibenzoic acid)… read more here.
Keywords: h2o; coordination polymers; syntheses structures; solvothermal syntheses ... See more keywords
Homochiral diamond frameworks embedding helixes: Syntheses, structures and properties
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DOI: 10.1016/j.jssc.2019.120896
Abstract: Abstract A pair of homochiral metal−organic frameworks [Cd((R)-HCIA) (1,4-DMIB)]·xGuest (1-D; (R)-H3CIA=(R)-5-(1-carboxyethoxy)isophthalic acid, 1,4- DMIB=1,1'-(2,5-dimethyl-1,4-phenylene)bis(4-methyl-1H-imidazole)) and [Cd((S)- HCIA)(1,4-DMIB)]·xGuest (1-L) were formed from Cd2+, H3CIA and 1,4-DMIB under solvothermal conditions, respectively. X-ray crystallography reveals they are enantiomers… read more here.
Keywords: diamond frameworks; helixes syntheses; embedding helixes; homochiral diamond ... See more keywords
Syntheses, structures, and properties of three mixed-ligand complexes based on 3,6-bis(imidazole-1-yl)pyridazine
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DOI: 10.1016/j.molstruc.2018.08.043
Abstract: Abstract Three new coordination polymers [Co(L)(1,2,4,5-BTC)0.5(H2O)]n (1), {[Ni(L)(1,2-BDC)(H2O)3]·H2O}n (2) and {[Zn3(L)2(1,3,5-BTC)2(H2O)2]·3H2O}n (3) [L = 3,6-bis(imidazole-1-yl)pyridazine, H4BTC = 1,2,4,5-Benzenetetracarboxylic acid, H2BDC = 1,2-Benzenedicarboxylic acid, H3BTC = 1,3,5-Benzenetricarboxylic acid] were synthesized based on a rigid ligand L and different aromatic carboxylic acid ligands under solvothermal… read more here.
Keywords: imidazole pyridazine; bis imidazole; ligand; syntheses structures ... See more keywords
Syntheses, structures, reactivity studies and properties of anionic water rich bivalent metal phthalates
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DOI: 10.1016/j.molstruc.2018.10.012
Abstract: Abstract The syntheses and crystal structures of three anionic water rich phthalates charge balanced by piperazinediium (pipH2)2+ viz. (pipH2)[M(H2O)4(pht)2]·8H2O [M = Ni (1), Co (2) and Cu(3)] (pht = phthalate) are reported. Reaction of 1–3 with imidazole (im) results… read more here.
Keywords: water rich; water; structures reactivity; h2o ... See more keywords
Syntheses and Structures of Arenethiolato Cobalt(II) Complexes Containing Acylamino Groups: Steric Effects of Bulky Ligands on Coordination and Geometry.
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DOI: 10.1021/acs.inorgchem.3c00849
Abstract: Bulky thiolato ligands have been developed for creating biomimetic model complexes of active sites in metalloenzymes. Herein, we report a series of di-ortho-substituted arenethiolato ligands containing bulky acylamino groups (RCONH; R = t-Bu-, (4-t-BuC6H4)3C-,{3,5-(Me2CH)2C6H3}3C-, and… read more here.
Keywords: acylamino groups; coordination; syntheses structures; geometry ... See more keywords
Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe).
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00530
Abstract: Three new quaternary lithium metal tellurites, Li3MTe4O11 (M = Al, Ga, and Fe), have been synthesized through hydrothermal and solid-state reactions by heating a mixture of LiOH·H2O, TeO2, and M2O3. The structures of the title… read more here.
Keywords: characterization quaternary; chemistry; syntheses structures; quaternary tellurites ... See more keywords
Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework.
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DOI: 10.1021/acs.inorgchem.8b01111
Abstract: Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via… read more here.
Keywords: complexes electron; coinage metal; syntheses structures; structures d10 ... See more keywords