One-Step Synthesis of Acylborons from Acyl Chlorides through Copper-Catalyzed Borylation with Polystyrene-Supported PPh3 Ligand.
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DOI: 10.1021/acs.orglett.2c02305
Abstract: We developed a one-step synthesis of acylborons from both readily available acyl chlorides and bis(pinacolato)diboron through copper(I)-catalyzed borylation. Under the reaction conditions using tBuOLi, polystyrene-supported triphenylphosphine as a copper ligand was found to promote the… read more here.
Keywords: synthesis acylborons; one step; synthesis; borylation ... See more keywords