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Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.03.089
Abstract: Abstract A stereoselective synthesis of the C1-C14 fragment of thiomarinols is disclosed. The key steps include the stereoselective preparation of an allylic sulfide via a chloro sulfide by 1,2-asymmetric induction, ring-closing metathesis reaction, Kirmse-Doyle reaction…
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Keywords:
advanced intermediate;
thiomarinol antibiotics;
enroute thiomarinol;
intermediate enroute ... See more keywords
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Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b00456
Abstract: A new and flexible approach toward the synthesis of 6,12-guaianolide anticancer drugs such as trilobolides or thapsigargin has been developed that could be applied to the preparation of analogues with a modified ring system. The…
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Keywords:
advanced intermediate;
intermediate thapsigargin;
diastereoselective synthesis;
synthesis advanced ... See more keywords
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Published in 2018 at "Chimia"
DOI: 10.2533/chimia.2017.158
Abstract: The structure of porous silica particles can be reorganized without alteration of the particle size and shape by the process of pseudomorphic transformation. Partial pseudomorphic transformation leads to ordered mesoporous silica with bimodal pore size…
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Keywords:
partial pseudomorphic;
pseudomorphic transformation;
advanced mesoporous;
transformation ... See more keywords
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Published in 2023 at "Materials"
DOI: 10.3390/ma16031036
Abstract: Huge amounts of vegetable waste, mainly resulting from the food industry, need large areas for storage, as they could cause hazardous environmental impact, leading to soil and water pollution or to CO2 emissions during accidental…
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Keywords:
carbon;
waste;
synthesis advanced;
green synthesis ... See more keywords