Copper‐Catalysed Synthesis of (E)‐Allylic Organophosphorus Derivatives: A Low Toxic, Mild, Economical, and Ligand‐Free Method
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DOI: 10.1002/cssc.202401450
Abstract: Abstract Organophosphorus compounds are fundamental for the chemical industry due to their broad applications across multiple sectors, including pharmaceuticals, agrochemicals, and materials science. Despite their high importance, the sustainable and cost‐effective synthesis of organophoshoryl derivatives… read more here.
Keywords: organophosphorus derivatives; allylic organophosphorus; synthesis allylic; organophosphorus ... See more keywords
Homoallylboration of Aldehydes: Stereoselective Synthesis of Allylic-Substituted Alkenes and E-Alkenes.
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DOI: 10.1021/acs.orglett.2c01789
Abstract: Cyclopropanated allylboration reagents participate in the homoallylation of aliphatic and aromatic aldehydes, generating substituted alkenes that are difficult to produce via other methods. In this study, we explored the scope and reactivity of homoallylation with… read more here.
Keywords: homoallylboration aldehydes; aldehydes stereoselective; allylic substituted; stereoselective synthesis ... See more keywords
Regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes catalyzed by CuCl under aerobic conditions.
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DOI: 10.1039/d5cc05099e
Abstract: An effective method for the regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes with the CuCl/HBpin system under air is described herein. This reaction features mild conditions, excellent regioselectivity and broad substrate scope, as various… read more here.
Keywords: allylic propargylic; dienes enynes; propargylic alcohols; synthesis allylic ... See more keywords