Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(21)63853-6
Abstract: Abstract Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective. In this respect, catalytic deoxygenative amide reduction has proven to be promising but challenging, as this approach… read more here.
Keywords: zirconium hydride; bond cleavage; hydride catalyzed; selective hydroboration ... See more keywords
The Asymmetric Synthesis of Amines via Nickel-Catalyzed Enantioconvergent Substitution Reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c13034
Abstract: Chiral dialkyl carbinamines are important in fields such as organic chemistry, pharmaceutical chemistry, and biochemistry, serving for example as bioactive molecules, chiral ligands, and chiral catalysts. Unfortunately, most catalytic asymmetric methods for synthesizing dialkyl carbinamines… read more here.
Keywords: nickel; synthesis; chemistry; synthesis amines ... See more keywords
Continuous flow synthesis of amines from the cascade reactions of nitriles and carbonyl-containing compounds promoted by Pt-modified titania catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Green Chemistry"
DOI: 10.1039/c8gc03037e
Abstract: A Pt-modified titania-based catalyst was successfully applied in the synthesis of amines employing several carbonyl containing molecules and nitriles. read more here.
Keywords: modified titania; flow synthesis; continuous flow; synthesis amines ... See more keywords
Decarboxylative Umpolung Synthesis of Amines from Carbonyl Compounds
Sign Up to like & getrecommendations! Published in 2020 at "Synlett"
DOI: 10.1055/s-0040-1707157
Abstract: 2-Azaallyl anions are valuable intermediates which have versatile applications in functionalization with various electrophiles. Decarboxylation of the imines formed from aromatic aldehydes and α,α-diphenylglycine provides an interesting and efficient way to generate delocalized 2-azaallyl anions,… read more here.
Keywords: amines carbonyl; synthesis amines; decarboxylative umpolung; carbonyl compounds ... See more keywords