Synthesis of an anionic Au(I) hydroamination precatalyst supported by charged hydrido-carboranyl phosphine ligands
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.09.027
Abstract: Abstract Herein is reported the synthesis of an anionic gold complex bearing two charged hydrido carboranyl phosphine ligands. The compound is fully characterized by multinuclear NMR spectroscopy, high resolution mass spectrometry, as well as a… read more here.
Keywords: carboranyl; hydrido carboranyl; charged hydrido; carboranyl phosphine ... See more keywords
Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03111a
Abstract: Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){(MesBIAN)Co(η4-cod)}] (1, MesBIAN = bis(mesityliminoace-naphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertex closo-cobaltacarborane cluster (2) in one step. The mechanism of this transformation has been studied by experimental and quantum… read more here.
Keywords: cobaltacarborane cluster; vertex closo; anionic vertex; synthesis anionic ... See more keywords