Synthesis of Arenesulfonyl Fluorides via Sulfuryl Fluoride Incorporation from Arynes.
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DOI: 10.1021/acs.orglett.8b03610
Abstract: Transition-metal-free multicomponent reactions involving aryne precursors, secondary amines, and sulfuryl fluoride are reported herein. Zwitterionic intermediates formed from the reaction of arynes with amine nucleophiles can capture SO2F2 under mild conditions, offering a novel and… read more here.
Keywords: fluorides via; synthesis arenesulfonyl; via sulfuryl; fluoride incorporation ... See more keywords