A Unifying Bioinspired Synthesis of (−)-Asperaculin A and (−)-Penifulvin D
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DOI: 10.1021/acs.orglett.1c00955
Abstract: The first syntheses of the isomeric dioxafenestrene natural products (−)-asperaculin A and (−)-penifulvin D are reported. Each target is formed selectively by choice of oxidant in a final divergent bioinspired Baeyer–Villiger (BV) reaction. Density functional… read more here.
Keywords: bioinspired synthesis; penifulvin; synthesis asperaculin; unifying bioinspired ... See more keywords