Asymmetric Total Synthesis of (-)-Astakolactin and Confirmation of Its Stereostructure.
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DOI: 10.1021/acs.jnatprod.7b00368
Abstract: The originally proposed structure of astakolactin was revised, and an asymmetric total synthesis of the newly proposed structure was achieved. The key transformations in the synthesis were a Johnson-Claisen rearrangement, an asymmetric Mukaiyama aldol reaction,… read more here.
Keywords: asymmetric total; total synthesis; astakolactin confirmation; synthesis astakolactin ... See more keywords