Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-26002-7
Abstract: The synthesis of phosphines is based on white phosphorus, which is usually converted to PCl3, to be afterwards substituted step by step in a non-atomic efficient manner. Herein, we describe an alternative efficient transition metal-mediated… read more here.
Keywords: synthesis asymmetric; pentaphosphaferrocene mediated; white phosphorus; phosphorus ... See more keywords
Modular synthesis of asymmetric rylene derivatives
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Chemistry C"
DOI: 10.1039/c6tc05139a
Abstract: The modular synthesis of asymmetric rylenes from naphthalic anhydride derivatives is presented. Imidization, Suzuki–Miyaura coupling and cyclodehydrogenation reactions are utilized for the generation of novel functional rylenes with these three core transformations providing significant flexibility… read more here.
Keywords: methodology; synthesis asymmetric; modular synthesis; asymmetric rylene ... See more keywords
Photo-controlled one-pot strategy for the synthesis of asymmetric three-arm star polymers
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DOI: 10.1039/c9py00774a
Abstract: A one-pot tandem strategy for the synthesis of asymmetric star polymers was developed. Two wavelengths of light were used to provide spatial and temporal control for the reactions. A series of stars were synthesised using… read more here.
Keywords: strategy synthesis; star polymers; one pot; synthesis asymmetric ... See more keywords
Improved Synthesis of Asymmetric Curcuminoids and Their Assessment as Antioxidants
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DOI: 10.3390/molecules27082547
Abstract: In this paper, the syntheses of twelve asymmetric curcumin analogs using Pabon’s method are reported. Generally, the previously reported yields of asymmetric curcuminoids, such as 9a (53%), 9c (38%), and 9k (38%), have been moderate… read more here.
Keywords: improved synthesis; asymmetric curcuminoids; radical scavenging; assessment antioxidants ... See more keywords