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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00349
Abstract: We describe a formal synthesis of 10-aza-9-oxakalkitoxin, the hydroxalog of the cytotoxic marine natural product kalkitoxin, that features Mukaiyama Markovnikov silyl peroxidation of a terminal alkene and N-O bond formation as the central enabling steps.
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Keywords:
aza oxakalkitoxin;
synthesis aza;
bond formation;
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1
Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04127
Abstract: An efficient [4 + 1] annulation reaction between in situ generated azoalkene intermediates and α-bromocarbonyls has been established. A series of skeletally diverse aza-heterocycles with a functionalized quaternary center were obtained in up to 89%…
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Keywords:
synthesis aza;
annulation;
center;
chemodivergent synthesis ... See more keywords
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2
Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04151
Abstract: Cellular labeling through the use of dyes is of great interest to the biomedical sciences for the characterization of the location and distribution of biomolecules and also for the tracking of the course of biological…
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Keywords:
synthesis aza;
aza bodipys;
synthesis;
bodipys differential ... See more keywords