Articles with "synthesis azacoumestans" as a keyword



Photo by osheen_ from unsplash

Weakly Coordinating tert-Amide-Assisted Ru(II)-Catalyzed Synthesis of Azacoumestans via Migratory Insertion of Quinoid Carbene: Application in the Total Synthesis of Isolamellarins.

Sign Up to like & get
recommendations!
Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c01556

Abstract: A weakly coordinating tert-amide-directed straightforward method was developed for the synthesis of azacoumestans using the corresponding azaheterocycle derivatives and diazonaphthoquinones under cheap Ru(II)-catalyzed conditions. The reaction proceeds via migratory insertion of quinoid carbene and subsequent… read more here.

Keywords: synthesis azacoumestans; synthesis; via migratory; tert amide ... See more keywords