Synthesis of benzene derivatives with multiple PCl2 groups.
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DOI: 10.1002/cplu.202300072
Abstract: The chlorination of 1,2-diphosphinobenzene with PCl5 to 1,2-bis(dichlorophosphino)benzene (2) was performed with high yields (93%) despite the high number of P-H functions. The method was further applied to other phosphanes, enabling the first synthesis and… read more here.
Keywords: benzene; dichlorophosphino benzene; multiple pcl2; derivatives multiple ... See more keywords
Synthesis of Ru(II)–benzene complexes containing aroylthiourea ligands, and their binding with biomolecules and in vitro cytotoxicity through apoptosis
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DOI: 10.1039/c6nj03099h
Abstract: The reaction of [RuCl2(η6-benzene)]2 with aroylthiourea resulted in the formation of Ru(II) complexes of the type [RuCl2(η6-benzene)L] (L = monodentate aroylthiourea ligand). The complexes were well characterized using UV-Visible, FT-IR, NMR and mass spectroscopic techniques.… read more here.
Keywords: benzene complexes; apoptosis; synthesis benzene; using visible ... See more keywords