Synthesis of Biindene Derivatives via Pd-Catalyzed Alkene Difunctionalization Reactions.
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DOI: 10.1021/acs.orglett.4c01400
Abstract: The palladium-catalyzed cross-coupling of 2-allylphenyl triflate and related electrophiles with substituted indenes affords biindene derivatives in moderate to good yields with high selectivity for thermodynamically preferred alkene isomers. The transformations involve alkene nucleopalladation with indenyl… read more here.
Keywords: via catalyzed; catalyzed alkene; alkene difunctionalization; synthesis biindene ... See more keywords