Synthesis of the Bulky Phosphanide [P(SiiPr3)2]− and Its Stabilization of Low-Coordinate Group 12 Complexes
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c03134
Abstract: Here, we report an improved synthesis of the bulky phosphanide anion [P(SiiPr3)2]− in synthetically useful yields and its complexation to group 12 metals. The ligand is obtained as the sodium salt NaP(SiiPr3)21 in a 42%… read more here.
Keywords: bulky; group; synthesis; synthesis bulky ... See more keywords
Synthesis of bulky hydride ligands: m-terphenylborohydride complexes with trivalent uranium and neodymium.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt01076d
Abstract: Here we describe the first coordination complexes containing a bulky m-terphenyltrihydroborate ligand. Treating [UI3(thf)4] and NdCl3 with three equiv. of Li(H3BArtBu4)(Et2O) (where ArtBu4 = 2,6-(3,5-tBu2C6H3)2C6H3) yielded [M(H3BArtBu4)3(thf)2] (M = U and Nd). [U(H3BArtBu4)3(dme)2] is also… read more here.
Keywords: ligands terphenylborohydride; terphenylborohydride complexes; complexes trivalent; hydride ligands ... See more keywords