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Stereoselective synthesis of C12–C21 common fragment of thermolides 1–5

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1 Published in 2018 at "Tetrahedron Letters"

DOI: 10.1016/j.tetlet.2018.06.020

Abstract: Abstract A highly stereoselective synthesis of C12–C21 common fragment of thermolides 1–5 has been described. The salient features of the synthesis are the utilization of desymmetrization protocol, Barton-McCombie reaction, Brown’s asymmetric allylation and Wacker oxidation. read more here.

Keywords: common fragment; stereoselective synthesis; fragment thermolides; c21 common ... See more keywords

Synthesis of the C1–C12 Fragment of Calyculin C

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1 Published in 2018 at "Synthesis"

DOI: 10.1055/s-0037-1610387

Abstract: Calyculins are a class of highly cytotoxic metabolites originally isolated from the marine sponge Discodermia calyx. To date, a total of twelve different calyculins (A–J) and calyculinamides (A, B and F) have been described, the… read more here.

Keywords: c12; synthesis c12; fragment calyculin;