Metal Assisted Synthesis of Cationic Sulfidobismuth Cubanes in Ionic Liquids.
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DOI: 10.1002/open.202000246
Abstract: Bi2 S3 was dissolved in the presence of either AuCl/PtCl2 or AgCl in the ionic liquids [BMIm]Cl ⋅ xAlCl3 (BMIm=1-n-butyl-3-methylimidazolium; x=4-4.3) through annealing the mixtures at 180 or 200 °C. Upon cooling to room temperature, orange, air-sensitive crystals… read more here.
Keywords: metal assisted; metal; synthesis cationic; assisted synthesis ... See more keywords
Synthesis of Cationic Amphiphilic Surface-Block Polyester Dendrimers
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DOI: 10.1007/s10904-017-0651-4
Abstract: AbstractCationic amphiphilic polyester dendrimers possessing varied numbers of choline and alkyl chains on the periphery were synthesized and characterized. A combination of divergent and convergent synthetic routes was used to efficiently prepare the dendrimers. All… read more here.
Keywords: dendrimer; cationic amphiphilic; polyester; synthesis cationic ... See more keywords
Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties.
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DOI: 10.1021/acs.orglett.3c01341
Abstract: Here, a facile and selective synthesis method for cationic azatriphenylene derivatives was established by electrochemical intramolecular cyclization, where atom-economical C–H pyridination without a transition-metal catalyst or an oxidant is a key step. The proposed protocol… read more here.
Keywords: cationic azatriphenylene; azatriphenylene derivatives; pyridination; synthesis cationic ... See more keywords
One-step sustainable synthesis of cationic high-swelling polymers obtained from starch-derived maltodextrins
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DOI: 10.1039/d0ra10715h
Abstract: This paper reports a novel eco-friendly one-step synthesis of maltodextrin-based cationic polymers developed exploiting amine-mediated ring-opening reactions of water-soluble diglycidyl ethers. read more here.
Keywords: sustainable synthesis; synthesis cationic; step; one step ... See more keywords
Synthesis of Cationic Ruthenium(II) complex and non-enzymatic Glucose Sensor Properties
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DOI: 10.1039/d2nj05470a
Abstract: The new cationic ruthenium(II) complex (2) was synthesized by the reaction of N,N'-[1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)]bis(2-ethyl-6-methylaniline) and [RuCl2(p-cymene)]2, and fully characterized by NMR, FT-IR, single-crystal X-ray diffraction, ESI–MS, UV-vis, CV and thermal analysis... read more here.
Keywords: complex non; cationic ruthenium; synthesis cationic; ruthenium complex ... See more keywords
Synthesis of Cationic [4], [5], and [6]Azahelicenes with Extended π-Conjugated Systems
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DOI: 10.3390/catal13050912
Abstract: The scope of Rh-catalyzed C–C bond cleavage/annulation of biphenylene with various aromatic nitriles was studied. The subsequent Rh- and Ir-catalyzed C–H bond activation/annulation sequence of the formed 9-arylphenanthridines with alkynes gave rise to cationic [4],… read more here.
Keywords: azahelicenes extended; extended conjugated; conjugated systems; synthesis cationic ... See more keywords