3 a,6 a-Diaza-1,4-Diphosphapentalenes: Synthesis and Complexation with the Organic π-Acceptor 1,2,4,5-Tetracyanobenzene.
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DOI: 10.1002/cplu.202200438
Abstract: The reaction of PCl3 with diethyl ketazine and 4-phenylcyclohexanone azine results in the formation of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalenes which were reduced by magnesium in THF to give corresponding diazadiphosphapentalenes EtMeDDP and PhcHexDDP, containing two-coordinate phosphorus atoms. According… read more here.
Keywords: acceptor; tetracyanobenzene; complexation organic; diaza diphosphapentalenes ... See more keywords
1,3,4-Thiadiazole-based diamides: Synthesis and complexation properties
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DOI: 10.1016/j.molstruc.2017.06.057
Abstract: Abstract Aromatic diamides, derivative of 2,6-pyridinedicarboxylic acid and isophthalic acid, bearing 1,3,4-thiadiazole residue were prepared with satisfactory yields in conventional procedures and microwave stimulated reactions. X-ray structure of N,N′-bis(1,3,4-thiadiazol-2-yl)-2,6-pyridinedicarboxamide (2) DMSO solvate (2·DMSO) was described.… read more here.
Keywords: complexation properties; diamides synthesis; based diamides; synthesis complexation ... See more keywords
Synthesis and Complexation of a Free Germanide Bearing a Tridentate N-Heterocyclic Substituent
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DOI: 10.1021/acs.organomet.8b00630
Abstract: The tris-N-heterocycle germanide (tmim)Ge– (1) (tmimH3 = tris(3-methylindol-2-yl)methane) was synthesized by nucleophilic substitution for the tmim3– trianion on GeCl2·dioxane. In combination with the previously reported (tmim)Si– and (tmim)P analogues, it provides a convenient model for… read more here.
Keywords: synthesis complexation; complexation free; germanide; tmim tmim ... See more keywords