1-t-Butyl-1-phenyl-1-silacyclohexane: Synthesis, conformational analysis in gas and solution by GED, FT-IR and theoretical calculations
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121433
Abstract: Abstract 1-t-Butyl-1-phenyl-1-silacyclohexane 1, the first disubstituted silacyclohexane with the most bulky substituent, t-Bu group, at silicon, was synthesized via the sequence of reactions PhSiCl3 → Ph(Cl)Si(CH2)5 → Ph(t-Bu)Si(CH2)5, and its molecular structure and conformational preferences… read more here.
Keywords: silacyclohexane synthesis; phenyl silacyclohexane; butyl phenyl; gas ... See more keywords
Synthesis and conformational studies of short mixed γ/α-glycopeptides based on sugar γ3,3-amino acids
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DOI: 10.1016/j.tet.2017.10.038
Abstract: Abstract Carbohydrates bearing both amino and carboxylate groups could be useful for expanding the repertoire of monomers used for building foldamers. In this paper, we give a full account of the synthesis of small hybrid… read more here.
Keywords: amino; amino acids; conformational studies; sugar amino ... See more keywords
Synthesis and conformational analysis of N-aryl-N-(6-azulenyl)acetamides
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DOI: 10.1016/j.tetlet.2019.06.029
Abstract: Abstract The cis-trans conformational equilibrium of amides is of interest because it can be used to control functional activity. Here, we designed and synthesized a series of N-(3-thienyl)amides in order to study the factors affecting… read more here.
Keywords: aryl azulenyl; aryl; analysis aryl; conformational analysis ... See more keywords
Synthesis and Conformational Analysis of 10-Mesitylanthracene-1,8-diyl Oligomers
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DOI: 10.1055/s-0037-1609869
Abstract: Oligomers consisting of 10-mesitylanthracene-1,8-diyl units were synthesized by Ni-mediated coupling of the corresponding dibromide as new oligoarene compounds. The structures and properties of these oligomers were investigated by NMR and electronic spectroscopy. Conformational analyses with… read more here.
Keywords: diyl oligomers; conformational analysis; mesitylanthracene; analysis mesitylanthracene ... See more keywords
Synthesis and Conformational Characteristics of Calix[4]arene Oligomers
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DOI: 10.1246/bcsj.20210287
Abstract: Lower- and/or upper-rim functionalization of calix[4]arene realized a variety of calix[4]arene systems. Compared to these monomeric calix[4]arenes, covalently linked calix[4]arene oligomers have no... read more here.
Keywords: calix arene; synthesis conformational; characteristics calix; arene oligomers ... See more keywords
Synthesis, Conformational Analysis and ctDNA Binding Studies of Flavonoid Analogues Possessing the 3,5-di-tert-butyl-4-hydroxyphenyl Moiety
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DOI: 10.3390/antiox11112273
Abstract: Flavanones and their biochemical precursors, chalcones, are naturally occurring compounds and consist of privileged scaffolds used in drug discovery due to their wide range of biological activities. In this work, two novel flavanones (3 and… read more here.
Keywords: arylidene flavanone; ctdna; conformational analysis; flavanones arylidene ... See more keywords
Synthesis and Conformational Analysis of Fluorinated Uridine Analogues Provide Insight into a Neighbouring-Group Participation Mechanism
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DOI: 10.3390/molecules25235513
Abstract: Fluorinated nucleoside analogues have attracted much attention as anticancer and antiviral agents and as probes for enzymatic function. However, the lack of direct synthetic methods, especially for 2′,3′-dideoxy-2′,3′-difluoro nucleosides, hamper their practical utility. In order… read more here.
Keywords: group participation; mechanism; conformational analysis; neighbouring group ... See more keywords