Biomimetic Synthesis of Cyanogramides B and C.
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DOI: 10.1021/acs.orglett.2c00510
Abstract: Marinacarboline E and cyanogramides B and C from the marine-derived bacterium Actinoalloteichus cyanogriseus have been synthesized. The key step is the Baeyer-Villiger oxidation of marinacarboline E to a ketene aminal via O → N acetyl… read more here.
Keywords: synthesis cyanogramides; biomimetic synthesis;