Visible-Light-Induced Deoxygenation/Defluorination Protocol for Synthesis of γ,γ-Difluoroallylic Ketones.
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DOI: 10.1021/acs.orglett.9b04504
Abstract: Herein, we describe an efficient, practical photocatalytic deoxygenation/defluorination protocol for the synthesis of γ,γ-difluoroallylic ketones from commercially available aromatic carboxylic acids, triphenylphosphine, and α-trifluoromethyl alkenes. The protocol has good functional group tolerance and a broad… read more here.
Keywords: deoxygenation defluorination; difluoroallylic ketones; defluorination protocol; synthesis difluoroallylic ... See more keywords