All That metas─Synthesis of Dispersion Energy Donor-Substituted Benzenes.
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DOI: 10.1021/acs.orglett.2c02780
Abstract: We report a general and scalable method for the synthesis of all-meta-trisubstituted benzenes from readily available 3,5-disubstituted catechols. Oxidation and [4 + 2] cycloaddition with acetylene dienophiles generate a bicyclo[2.2.2]octane structure that is doubly decarbonylated… read more here.
Keywords: synthesis dispersion; metas synthesis; dispersion energy; synthesis ... See more keywords