Organophotoredox‐Catalyzed CDC Reactions for the Synthesis of Diverse Heterocycles via C─N and C─O Bond Formation under Visible Light Irradiation
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202500404
Abstract: An efficient construction of C═N and C─O bonds by the metal‐free organophotoredox catalyzed intramolecular cross‐dehydrogenative coupling of tertiary amines with amides, amines, and acids as nucleophiles is described. A series of 12,13‐dihydro‐6H‐isoquinolino[2,1‐a]quinazolin‐6‐one, 5,6‐dihydrobenzo[4,5]imidazo [2,1‐a]isoquinoline, and… read more here.
Keywords: cdc reactions; catalyzed cdc; reactions synthesis; organophotoredox catalyzed ... See more keywords
Unified Total Synthesis of Diverse Meroterpenoids from Ganoderma Applanatum.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01633
Abstract: A unified approach to meroterpenoids applanatumols B, V, W, X, and Y produced by the medicinal fungus Ganoderma applanatum and 2'-epi-spiroapplanatumine O is presented. The key synthetic sequence consists of a tandem anionic ketone allylation/oxy-Cope… read more here.
Keywords: unified total; meroterpenoids ganoderma; diverse meroterpenoids; total synthesis ... See more keywords
Synthesis of Diverse γ-Lactams via Rh-Catalyzed C(sp2)-H Addition to Aliphatic Nitriles.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01867
Abstract: We herein report an unprecedented pathway to access γ-lactams using acetonitrile analogues as coupling partners without oxidants, ligands, and Lewis acids. The reaction undergoes Rh-catalyzed C(sp2)-H addition to carbon-bound nitriles with the aid of an… read more here.
Keywords: sp2 addition; lactams via; synthesis diverse; catalyzed sp2 ... See more keywords
3-Thioaryne Intermediates for the Synthesis of Diverse Thioarenes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01862
Abstract: The synthetic utility of 3-thioaryne intermediates has been demonstrated through an aryne relay approach. The efficient synthesis of o-silylaryl triflate-type 3-thioaryne precursors has been achieved by the regioselective silylthiolation of 3-(triflyloxy)arynes with silyl sulfides. Various… read more here.
Keywords: diverse thioarenes; intermediates synthesis; synthesis diverse; thioaryne intermediates ... See more keywords
Synthesis of Diverse Green Carbon Nanomaterials through Fully Utilizing Biomass Carbon Source Assisted by KOH.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b08420
Abstract: With multiple properties, green carbon nanomaterials with high specific surface area have become extensively attractive as energy storage devices with environmental-friendly features. The primary synthesis attempts were based on alkalis activation, which, however, faced the… read more here.
Keywords: carbon; biomass; carbon nanomaterials; synthesis diverse ... See more keywords
Copper-catalyzed direct coupling of benzoxazin-2-ones with indoles for the synthesis of diverse 3-indolylbenzoxazin-2-ones: access to natural cephalandole A
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra10634c
Abstract: A novel and facile copper-catalyzed direct coupling for the synthesis of diverse and functionalized 3-indolyl benzoxazin-2-ones from benzoxazin-2-ones and indoles has been developed. This new methodology offers an easy and rapid approach to a variety… read more here.
Keywords: benzoxazin ones; ones indoles; direct coupling; synthesis diverse ... See more keywords
Rapid and High-Throughput Synthesis of Diverse MOFs with Centrifuge Tube Grinding Strategy
Sign Up to like & getrecommendations! Published in 2024 at "Green Chemistry"
DOI: 10.1039/d4gc00865k
Abstract: Green and economical synthetic approach for metal-organic frameworks (MOFs) and incorporating multiple functionalities into MOF matrixes are of great interests for wide applications. Herein, we developed a rapid, high-throughput and... read more here.
Keywords: high throughput; rapid high; synthesis diverse; throughput synthesis ... See more keywords
Photoinduced Core Skeletal Editing: Streamlined Strategies for the Synthesis of Diverse Cyclic Scaffolds
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DOI: 10.1055/a-2640-2657
Abstract: Skeletal editing is a novel approach for the synthesis of diverse molecular scaffolds that is currently under investigation in the field of drug discovery and modern synthetic chemistry. With the rise of photochemistry, recent years… read more here.
Keywords: photoinduced core; editing streamlined; synthesis diverse; skeletal editing ... See more keywords
Synthesis of Diverse Phenothiazines by Direct Thioamination of Arynes with S-(o-Bromoaryl)-S-methylsulfilimines and Subsequent Intramolecular Buchwald–Hartwig Amination
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry Letters"
DOI: 10.1246/cl.180304
Abstract: A facile method for the synthesis of diverse phenothiazines has been achieved by direct thioamination of aryne intermediates with S-(o-bromoaryl)-S-methylsulfilimines and subsequent intramolecular ... read more here.
Keywords: subsequent intramolecular; diverse phenothiazines; direct thioamination; methylsulfilimines subsequent ... See more keywords
Facile Synthesis of Diverse o-Iodoaryl Triflates from o-Silylaryl Triflates by Aluminum-mediated Desilyliodination
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DOI: 10.1246/cl.190223
Abstract: A convenient method for preparing diverse o-iodoaryl triflates by the desilyliodination of o-silylaryl triflates has been developed. The treatment of o-silylaryl triflates with 1,3-diiodo-5,5-dimet... read more here.
Keywords: facile synthesis; iodoaryl triflates; silylaryl triflates; diverse iodoaryl ... See more keywords
Efficient Multicomponent Synthesis of Diverse Antibacterial Embelin-Privileged Structure Conjugates
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25143290
Abstract: A library of embelin derivatives has been synthesized through a multicomponent reaction from embelin (1), aldehydes and privileged structures such as 4-hydroxycoumarin, 4-hydroxy-2H-pyran-2-one and 2-naphthol, in the presence of InCl3 as catalyst. This multicomponent reaction… read more here.
Keywords: efficient multicomponent; multicomponent synthesis; diverse antibacterial; synthesis diverse ... See more keywords