Unified Total Synthesis of Diverse Meroterpenoids from Ganoderma Applanatum.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01633
Abstract: A unified approach to meroterpenoids applanatumols B, V, W, X, and Y produced by the medicinal fungus Ganoderma applanatum and 2'-epi-spiroapplanatumine O is presented. The key synthetic sequence consists of a tandem anionic ketone allylation/oxy-Cope… read more here.
Keywords: unified total; meroterpenoids ganoderma; diverse meroterpenoids; total synthesis ... See more keywords
Synthesis of Diverse γ-Lactams via Rh-Catalyzed C(sp2)-H Addition to Aliphatic Nitriles.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01867
Abstract: We herein report an unprecedented pathway to access γ-lactams using acetonitrile analogues as coupling partners without oxidants, ligands, and Lewis acids. The reaction undergoes Rh-catalyzed C(sp2)-H addition to carbon-bound nitriles with the aid of an… read more here.
Keywords: sp2 addition; lactams via; synthesis diverse; catalyzed sp2 ... See more keywords
3-Thioaryne Intermediates for the Synthesis of Diverse Thioarenes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01862
Abstract: The synthetic utility of 3-thioaryne intermediates has been demonstrated through an aryne relay approach. The efficient synthesis of o-silylaryl triflate-type 3-thioaryne precursors has been achieved by the regioselective silylthiolation of 3-(triflyloxy)arynes with silyl sulfides. Various… read more here.
Keywords: diverse thioarenes; intermediates synthesis; synthesis diverse; thioaryne intermediates ... See more keywords
Synthesis of Diverse Green Carbon Nanomaterials through Fully Utilizing Biomass Carbon Source Assisted by KOH.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b08420
Abstract: With multiple properties, green carbon nanomaterials with high specific surface area have become extensively attractive as energy storage devices with environmental-friendly features. The primary synthesis attempts were based on alkalis activation, which, however, faced the… read more here.
Keywords: carbon; biomass; carbon nanomaterials; synthesis diverse ... See more keywords
Copper-catalyzed direct coupling of benzoxazin-2-ones with indoles for the synthesis of diverse 3-indolylbenzoxazin-2-ones: access to natural cephalandole A
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra10634c
Abstract: A novel and facile copper-catalyzed direct coupling for the synthesis of diverse and functionalized 3-indolyl benzoxazin-2-ones from benzoxazin-2-ones and indoles has been developed. This new methodology offers an easy and rapid approach to a variety… read more here.
Keywords: benzoxazin ones; ones indoles; direct coupling; synthesis diverse ... See more keywords
Synthesis of Diverse Phenothiazines by Direct Thioamination of Arynes with S-(o-Bromoaryl)-S-methylsulfilimines and Subsequent Intramolecular Buchwald–Hartwig Amination
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry Letters"
DOI: 10.1246/cl.180304
Abstract: A facile method for the synthesis of diverse phenothiazines has been achieved by direct thioamination of aryne intermediates with S-(o-bromoaryl)-S-methylsulfilimines and subsequent intramolecular ... read more here.
Keywords: subsequent intramolecular; diverse phenothiazines; direct thioamination; methylsulfilimines subsequent ... See more keywords
Facile Synthesis of Diverse o-Iodoaryl Triflates from o-Silylaryl Triflates by Aluminum-mediated Desilyliodination
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DOI: 10.1246/cl.190223
Abstract: A convenient method for preparing diverse o-iodoaryl triflates by the desilyliodination of o-silylaryl triflates has been developed. The treatment of o-silylaryl triflates with 1,3-diiodo-5,5-dimet... read more here.
Keywords: facile synthesis; iodoaryl triflates; silylaryl triflates; diverse iodoaryl ... See more keywords
Efficient Multicomponent Synthesis of Diverse Antibacterial Embelin-Privileged Structure Conjugates
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DOI: 10.3390/molecules25143290
Abstract: A library of embelin derivatives has been synthesized through a multicomponent reaction from embelin (1), aldehydes and privileged structures such as 4-hydroxycoumarin, 4-hydroxy-2H-pyran-2-one and 2-naphthol, in the presence of InCl3 as catalyst. This multicomponent reaction… read more here.
Keywords: efficient multicomponent; multicomponent synthesis; diverse antibacterial; synthesis diverse ... See more keywords