Synthesis, dynamics and redox properties of eight-coordinate zirconium catecholate complexes.
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DOI: 10.1039/d0dt02487b
Abstract: Reaction of the 9,9-dimethylxanthene-bis(imine)-bis(catechol) ligand XbicH4 with half an equivalent of Zr(acac)4 affords the neutral tetracatecholate complex (XbicH2)2Zr, containing four iminium ions hydrogen bonded to the catecholates. The heteroleptic bis(catecholate)-tetraphenylporphyrin complex (TPP)Zr(XbicH2) is formed from… read more here.
Keywords: xbich2; synthesis dynamics; zirconium; eight coordinate ... See more keywords