Synthesis and Electronic Properties of Triperyleno[3.3.3]Propellanes: Towards Two-Dimensional Electronic Structures.
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DOI: 10.1002/cplu.201800614
Abstract: Threefold symmetric triperyleno[3.3.3]propellanes (TPRPs), which are composed of three perylene units peri-fused on [3.3.3]proppellane, have been synthesized and their electronic properties characterized. Unsubstituted TPRP assembles into two-dimensional honeycomb-like networks. TPRP displays a bathochromic-shifted absorption band… read more here.
Keywords: properties triperyleno; synthesis electronic; triperyleno propellanes; propellanes towards ... See more keywords
Synthesis and electronic properties of pyridine end-capped cyclopentadithiophene-vinylene oligomers
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DOI: 10.1039/d0ra08220a
Abstract: A series of four oligomers of cyclopentadithiophene-vinylenes end capped with pyridine groups was prepared and their optical and electronic properties studied. Treatment with trifluoroacetic acid (TFA) leads to the bisprotonation of the nitrogens of the… read more here.
Keywords: synthesis electronic; electronic properties; pyridine end; capped cyclopentadithiophene ... See more keywords
Synthesis and electronic properties of nitrogen-doped π-extended polycyclic aromatic dicarboximides with multiple redox processes
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DOI: 10.1039/d1tc01239h
Abstract: A series of novel nitrogen-doped polycyclic aromatic mono and dicarboximides, able to stabilize multiple redox processes, has been synthesized by an innovative procedure that avoids metal-based cross-coupling reactions. read more here.
Keywords: nitrogen doped; synthesis electronic; multiple redox; redox processes ... See more keywords
Synthesis, electronic nature, and reactivity of selected silylene carbonyl complexes.
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DOI: 10.1039/d2dt01335e
Abstract: Room-temperature stable main group element carbonyl complexes are rare. Here we report on the synthesis of two such complexes, namely gallium-substituted silylene-carbonyl complexes [L(X)Ga]2SiCO (X = I 2, Me 3; L = HC[C(Me)NDipp]2, Dipp =… read more here.
Keywords: silylene carbonyl; carbonyl; electronic nature; carbonyl complexes ... See more keywords