Enantioselective Total Synthesis of (+)-Euphorikanin A.
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DOI: 10.1021/jacs.1c04210
Abstract: We disclose the first total synthesis of (+)-euphorikanin A, an ingenane-derived natural product featuring an unprecedented 5/6/7/3-fused tetracyclic skeleton. Key to the approach is a SmI2-mediated ketyl-enoate reaction that leads to the formation of two… read more here.
Keywords: total synthesis; synthesis euphorikanin; enantioselective total; synthesis ... See more keywords