Asymmetric Total Synthesis of (−)-GuignardonesA and B
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DOI: 10.1021/acs.orglett.0c00241.s001
Abstract: The asymmetric total synthesis of (−)-guignardones A (2) and B (1) has been accomplished. The highly oxidized 6-oxabicyclo[3.2.1]octane core was constructed from d-quinic acid via substitution/desulfurization reaction with thiophenol to forge the bridged ring scaffold,… read more here.
Keywords: asymmetric total; synthesis guignardonesa; total synthesis;