Controllable Stereoselective Synthesis of (Z)- and (E)-Homoallylic Alcohols Using a Palladium-Catalyzed Three-Component Reaction.
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DOI: 10.1021/acs.orglett.7b02979
Abstract: Diastereoselective synthesis of (Z)- and (E)-homoallylic alcohols using a Pd-catalyzed three-component reaction of 3-(pinacolatoboryl)allyl benzoates, aldehydes, and aryl stannanes was developed, which provides an alternative method for the allylboration of aldehydes using α,γ-diaryl-substituted allylboronates. Both… read more here.
Keywords: synthesis homoallylic; catalyzed three; homoallylic alcohols; three component ... See more keywords
Cobalt-catalyzed Synthesis of Homoallylic Amines from Imines and Terminal Alkenes
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DOI: 10.1246/cl.190378
Abstract: Homoallylic amines are important synthetic targets in organic synthesis. Compared to other conventional allylation reactions using pre-functionalized allylic compounds, the allylation of imines usi... read more here.
Keywords: synthesis; synthesis homoallylic; amines imines; homoallylic amines ... See more keywords