Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes.
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DOI: 10.1039/c8cc05234d
Abstract: The reaction of LnI2(thf)2 with benzyl potassium affords the homoleptic benzyl complexes [Ln(CH2Ph)2]n of samarium, europium, and ytterbium. In the cases of Eu and Yb, the treatment of [Ln(CH2Ph)2]n with one equivalent of 2,6-diisopropylaniline gives… read more here.
Keywords: lanthanide organoimides; benzyl; divalent lanthanide; synthesis homometallic ... See more keywords