Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes.
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DOI: 10.1039/c8dt04278k
Abstract: A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S',S''-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S',S''-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of… read more here.
Keywords: ligand substitution; synthesis ligand; substitution reactions; reactions ruthenaboratranes ... See more keywords
Facile Synthesis of Ligand-Free Iridium Nanoparticles and Their In Vitro Biocompatibility
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DOI: 10.1186/s11671-018-2621-3
Abstract: High-density inorganic nanoparticles have shown promise in medical applications that utilize radiation including X-ray imaging and as radiation dose enhancers for radiotherapy. We have developed an aqueous synthetic method to produce small (~ 2 nm) iridium nanoparticles… read more here.
Keywords: ligand free; iridium; facile synthesis; iridium nanoparticles ... See more keywords