A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes.
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DOI: 10.1021/acs.orglett.0c04175
Abstract: Direct catalytic transformation of chlorosilanes into organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). We herein report the palladium-catalyzed cross-coupling reaction of chlorosilanes with organoaluminum reagents. A combination of [Pd(C3H5)Cl]2… read more here.
Keywords: synthesis methylmonochlorosilanes; selective synthesis; general selective; tri tetrachlorosilanes ... See more keywords