Bioinspired Synthesis of Microstegiol and Biosynthetically Related Skeleton-Rearranged Abietanes.
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DOI: 10.1021/acs.orglett.5c00033
Abstract: We report a bioinspired synthesis of microstegiol and biosynthetically related skeleton-rearranged abietane diterpenoids from commercially available carnosic acid. The strategy features a Wagner-Meerwein type methyl migration followed by several cascade transformations, enabling the divergent synthesis… read more here.
Keywords: related skeleton; synthesis microstegiol; synthesis; bioinspired synthesis ... See more keywords