Synthesis of Oligo(1,8-pyrenylene)s: A Series of Functional Molecular Liquids.
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DOI: 10.1002/cplu.201900133
Abstract: A monomer-through-pentamer series of oligo(1,8-pyrenylene)s was synthesized using a two-step iterative synthetic strategy. The trimer, tetramer, and pentamer are mixtures of atropisomers that interconvert slowly at room temperature (as shown by variable-temperature NMR analysis). They… read more here.
Keywords: oligo pyrenylene; functional molecular; series functional; pyrenylene series ... See more keywords
Synthesis of Oligo-(alkyne-triplet)peptide Constructs.
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DOI: 10.1021/acs.orglett.7b03231
Abstract: Copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click synthesis of an Fmoc-(trispropargyl)amino acid building block for solid phase peptide synthesis (SPPS) of oligo-(trialkyne)peptide constructs is reported. These can carry potentially indefinite numbers of inherent alkyne-triplets, which are click… read more here.
Keywords: synthesis; synthesis oligo; peptide constructs; alkyne triplet ... See more keywords
On-Surface Synthesis of Oligo(indenoindene).
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DOI: 10.1021/jacs.0c05701
Abstract: Fully conjugated ladder polymers (CLP) possess unique optical and electronic properties, and are considered promis-ing materials for applications in (opto)electronic devices. Poly(indenoindene) is a CLP consisting of an alternating array of five- and six-membered rings,… read more here.
Keywords: surface synthesis; oligo indenoindene; synthesis oligo; microscopy ... See more keywords
P-stereocontrolled synthesis of oligo(nucleoside N3′→O5′ phosphoramidothioate)s – opportunities and limitations
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DOI: 10.1039/d0ra04987e
Abstract: 3′-N-(2-Thio-1,3,2-oxathiaphospholane) derivatives of 5′-O-DMT-3′-amino-2′,3′-dideoxy-ribonucleosides (NOTP-N), that bear a 4,4-unsubstituted, 4,4-dimethyl, or 4,4-pentamethylene substituted oxathiaphospholane ring, were synthesized. Within these three series, NOTP-N differed by canonical nucleobases (i.e., AdeBz, CytBz, GuaiBu, or Thy). The monomers were… read more here.
Keywords: phosphoramidothioate; synthesis oligo; oligo nucleoside; phosphoramidothioate opportunities ... See more keywords