Bioinspired synthesis of pentalene-based chromophores from an oligoketone chain.
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DOI: 10.1039/c8cc02379d
Abstract: We report a bioinspired synthesis of 2,5-dihydropentalene-based chromophores from an aliphatic oligoketone bearing 1,3- and 1,4-diketone subunits. Unlike the natural polyketone sequence, fused five-membered rings were formed via an intramolecular aldol condensation. A subsequent Knoevenagel… read more here.
Keywords: pentalene based; chain; bioinspired synthesis; synthesis pentalene ... See more keywords