A bioinspired, one-step total synthesis of peshawaraquinone
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DOI: 10.1039/d2sc05377b
Abstract: A concise synthesis of a stereochemically complex meroterpenoid, peshawaraquinone, via the unsymmetrical dimerization of its achiral precursor, dehydro-α-lapachone, is reported. Enabled by reversible oxa-6π-electrocyclizations of 2H-pyran intermediates, the base-catalyzed dimerization sets up an intramolecular (3… read more here.
Keywords: synthesis peshawaraquinone; peshawaraquinone; one step; synthesis ... See more keywords