Concise Total Synthesis of Peyssonnoside A.
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DOI: 10.1021/jacs.1c07135
Abstract: Peyssonnoside A is a marine-derived sulfated diterpenoid glucoside with a unique 5/6/3/6 tetracyclic skeleton with a highly substituted cyclopropane ring deeply embedded into the structure. Herein, we report the first total synthesis of this natural… read more here.
Keywords: total synthesis; synthesis peyssonnoside; concise total; synthesis ... See more keywords
Catalysis-Enabled 13-Step Total Synthesis of (-)-Peyssonnoside A.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09919
Abstract: We report a 13-step enantioselective and stereoselective total synthesis of (-)-peyssonnoside A, a unique diterpene glucoside with a rare and highly congested pentasubstituted cyclopropane and promising antimicrobial activity. Among the 10 steps to synthesize (-)-peyssonnosol,… read more here.
Keywords: step; synthesis peyssonnoside; peyssonnoside; catalysis enabled ... See more keywords