Synthesis and photochemical study of tricarbonyl and dicarbonyl derivatives of 3-cymantrenylalkylisothioureas
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121465
Abstract: Abstract A series of 3-cymantrenylalkylisothioureas (2) was synthesized. DFT calculations showed that compounds 2 in solutions are dimers. The photolysis of 2 was studied by IR, UV–vis and NMR spectroscopic methods. Irradiation of compounds 2… read more here.
Keywords: dicarbonyl; synthesis photochemical; photochemical study; study tricarbonyl ... See more keywords
Substituted Dibenzodiazocines: Rapid Synthesis and Photochemical Properties
Sign Up to like & getrecommendations! Published in 2021 at "ACS Omega"
DOI: 10.1021/acsomega.1c02524
Abstract: 11,12-Dihydrodibenzo[c,g]-1,2-diazocines have been established as a viable alternative to azobenzene for photoswitching, in particular, as they show an inverted switching behavior: the ground state is the Z isomer. In this paper, we present an improved… read more here.
Keywords: dibenzodiazocines rapid; synthesis photochemical; rapid synthesis; system ... See more keywords
Synthesis and photochemical properties of caged peroxides for photocontrol of cellular oxidative stress.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01192e
Abstract: We developed a caged hydroperoxide, BhcTBHP, releasing prooxidant TBHP under blue light irradiation. MitoTBHP with triphenylphosphonium at position 7 triggered selective oxidative stress and membrane depolarization in mitochondria upon photoirradiation. This study presents a powerful… read more here.
Keywords: caged peroxides; stress; oxidative stress; synthesis photochemical ... See more keywords
Some new bis-1,4 pentazadienes: synthesis and photochemical properties
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Crystals and Liquid Crystals"
DOI: 10.1080/15421406.2018.1542109
Abstract: Abstract The synthesis of some new bis-1,4-pentazadienes and their photolytic decomposition are described. The uniformity of photolysis reactions is studied by the AD-diagram method. It was found that the photolysis on the later stages does… read more here.
Keywords: bis pentazadienes; synthesis photochemical; pentazadienes synthesis; new bis ... See more keywords
Isoxazolyl-Derived 1,4-Dihydroazolo[5,1-c][1,2,4]Triazines: Synthesis and Photochemical Properties
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28073192
Abstract: New fluorescent dyes containing an assembled 1,4-dihydroazolo[5,1-c][1,2,4]triazine (DAT) core and an isoxazole ring were synthesized through a reaction between diazopyrazole or diazoimidazoles and isoxazolyl-derived enamines in mild conditions. The photophysical characteristics (maxima absorption and emission,… read more here.
Keywords: triazines synthesis; isoxazolyl derived; derived dihydroazolo; synthesis photochemical ... See more keywords