LAUSR

Synthesis and Reactivity of Thiolate‐Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP2S2 Metalloligand

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1 Published in 2017 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.201700937

Abstract: Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex into two different types of… read more here.

Keywords: thiolate bridged; niiimi heterodinuclear; heterodinuclear complexes; reactivity thiolate ... See more keywords

Synthesis and Reactivity of 3-oxoprop-1-en-1-olate Derivative as a Building Block for the Synthesis of Azole and Azine Derivatives

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0 Published in 2017 at "Journal of Heterocyclic Chemistry"

DOI: 10.1002/jhet.2775

Abstract: Several new heterocyclic compounds such as 7-substituted pyrazolo[1,5-a]pyrimidine (5a–e) derivatives have been synthesized by the reactions of the versatile unreported sodium 3-(4-methyl-2-(4-methylphenylsulfonamido)thiazol-5-yl)-3-oxoprop-1-en-1-olate (2) with amino heterocyclic (3a–e) derivatives. Reaction of (2) with hydrazonyl halide (7a–d)… read more here.

Keywords: oxoprop; olate derivative; reactivity oxoprop; oxoprop olate ... See more keywords

Synthesis and reactivity of aminofuroxans

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0 Published in 2019 at "Chemistry of Heterocyclic Compounds"

DOI: 10.1007/s10593-019-02593-4

Abstract: In this review article, we provide general information on the known methods for directed synthesis of 3- and 4-aminofuroxans, as well as analyze the main aspects of their reactivity. Methods for regio- and chemoselective transformations… read more here.

Keywords: synthesis reactivity; reactivity aminofuroxans; reactivity; chemistry ... See more keywords

Synthesis and Reactivity Studies of a [Cp*Rh] Complex Supported by a Methylene-Bridged Hybrid Phosphine-Imine Ligand.

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0 Published in 2020 at "Journal of organometallic chemistry"

DOI: 10.1016/j.jorganchem.2020.121294

Abstract: [Cp*Rh] complexes (Cp* = η 5-pentamethylcyclopentadienyl) supported by bidentate chelating ligands are useful in studies of redox chemistry and catalysis, but little information is available for derivatives bearing "hybrid" [P,N] chelates. Here, the preparation, structural… read more here.

Keywords: chemistry; reactivity; methylene; reactivity studies ... See more keywords

Synthesis and reactivity of new amide-substituted oxindole derivatives

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0 Published in 2017 at "Tetrahedron"

DOI: 10.1016/j.tet.2017.10.049

Abstract: Abstract Oxindole derivatives are of growing importance in organic synthesis and in the synthesis of biologically active compounds, therefore, a very important goal is to develop new ways of modifying such scaffold. In this article… read more here.

Keywords: amide substituted; oxindole derivatives; group; reactivity new ... See more keywords

Synthesis and Reactivity of Triangular Heterometallic Complexes Containing Zn-Zn Bond.

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1 Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c00956

Abstract: This work provides a facile access to a series of triangular [Zn2M] (M = group 10 and 11 metals) clusters. Treatment of Zn-Zn-bonded compounds [LZn-ZnL] (L = CH3C(2,6-iPr2C6H3N)CHC(CH3)(NCH2CH2PR2); R = Ph, iPr) with zero-valent transition-metal… read more here.

Keywords: heterometallic complexes; triangular heterometallic; reactivity triangular; synthesis reactivity ... See more keywords

Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand

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0 Published in 2020 at "Organometallics"

DOI: 10.1021/acs.organomet.0c00018

Abstract: Two methods for the synthesis of the bis(imidazolin-2-ylidene)carbazolide cobalt(I) complex [Co(bimcaHomo)] (2) have been developed. The first route relies on the direct transmetalation of the in s... read more here.

Keywords: cobalt; reactivity cobalt; cobalt iridium; iridium complexes ... See more keywords

Synthesis, Reactivity, and Insights into the Lewis Acidity of Mononuclear Titanocene Imido Complexes Bearing Sterically Demanding Terphenyl Moieties

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0 Published in 2020 at "Organometallics"

DOI: 10.1021/acs.organomet.0c00452

Abstract: The titanocene imido complex 2 with a m-terphenyl moiety is synthesized by reacting Cp2Ti(η2-Me3SiC2SiMe3) (1) with m-terphenyl azide. Subsequent reactivity studies with tetrahydrofuran, pyridine, ... read more here.

Keywords: imido; insights lewis; reactivity insights; synthesis reactivity ... See more keywords

Synthesis and Reactivity of Metal–Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for β-Alkylation of Secondary Alcohols with Primary Alcohols

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0 Published in 2018 at "Organometallics"

DOI: 10.1021/acs.organomet.8b00432

Abstract: Three unsymmetrical NNN ligands with a 2-hydroxypyridyl fragment were used to react with RuHCl(PPh3)3(CO), affording the three bidentate ruthenium hydride complexes [(R1-C5H3N-CH2-C5H3N-C5H3N-R2)Ru... read more here.

Keywords: hydride complexes; ruthenium hydride; synthesis reactivity; reactivity metal ... See more keywords

Synthesis and Reactivity of IrIII Complexes Bearing C-Metalated Pyrazolato Ligands

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0 Published in 2019 at "Organometallics"

DOI: 10.1021/acs.organomet.8b00856

Abstract: A bidentate triazolinylidene-pyrazole chelate ligand was metalated with [IrCp*Cl2]2 to give C,N-chelate complex [4]I. The N1-metalated pyrazole subsequently underwent a rollover metalation to give the complex with C5,C4-metalated pyrazolato ligand [5]. The reactivity of [5]… read more here.

Keywords: reactivity iriii; synthesis reactivity; metalated pyrazolato; reactivity ... See more keywords

Synthesis and Reactivity of 1-Hydroxyherquline A.

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1 Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c00379

Abstract: Herein, we present the synthesis of 1-hydroxyherquline A and describe its reactivity discovered during its attempted conversion to herquline A, a long-sought natural product target in the synthetic chemical community. The strategic installation of the… read more here.

Keywords: reactivity hydroxyherquline; synthesis reactivity; herquline; reactivity ... See more keywords