Synthesis and Reactivity of Thiolate‐Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP2S2 Metalloligand
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700937
Abstract: Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex into two different types of… read more here.
Keywords: thiolate bridged; niiimi heterodinuclear; heterodinuclear complexes; reactivity thiolate ... See more keywords
SYNTHESIS AND REACTIVITY OF CARBOHYDRATES CONTAINING 3‐MEMBERED HETEROCYCLES, KEY PRECURSORS OF MODIFIED SUGARS AND MIMETICS
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400488
Abstract: Molecules containing three‐membered heterocycles, including oxiranes (epoxides), thiiranes (episulfides) and aziridines, are considered privileged structures as they serve as key precursors or intermediates for the synthesis of a varied range of organic compounds, such as… read more here.
Keywords: synthesis reactivity; key precursors; membered heterocycles; ring opening ... See more keywords
Synthesis and Reactivity of 3-oxoprop-1-en-1-olate Derivative as a Building Block for the Synthesis of Azole and Azine Derivatives
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DOI: 10.1002/jhet.2775
Abstract: Several new heterocyclic compounds such as 7-substituted pyrazolo[1,5-a]pyrimidine (5a–e) derivatives have been synthesized by the reactions of the versatile unreported sodium 3-(4-methyl-2-(4-methylphenylsulfonamido)thiazol-5-yl)-3-oxoprop-1-en-1-olate (2) with amino heterocyclic (3a–e) derivatives. Reaction of (2) with hydrazonyl halide (7a–d)… read more here.
Keywords: oxoprop; olate derivative; reactivity oxoprop; oxoprop olate ... See more keywords
Synthesis and reactivity of aminofuroxans
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-019-02593-4
Abstract: In this review article, we provide general information on the known methods for directed synthesis of 3- and 4-aminofuroxans, as well as analyze the main aspects of their reactivity. Methods for regio- and chemoselective transformations… read more here.
Keywords: synthesis reactivity; reactivity aminofuroxans; reactivity; chemistry ... See more keywords
Synthesis and Reactivity Studies of a [Cp*Rh] Complex Supported by a Methylene-Bridged Hybrid Phosphine-Imine Ligand.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of organometallic chemistry"
DOI: 10.1016/j.jorganchem.2020.121294
Abstract: [Cp*Rh] complexes (Cp* = η 5-pentamethylcyclopentadienyl) supported by bidentate chelating ligands are useful in studies of redox chemistry and catalysis, but little information is available for derivatives bearing "hybrid" [P,N] chelates. Here, the preparation, structural… read more here.
Keywords: chemistry; reactivity; methylene; reactivity studies ... See more keywords
Synthesis and reactivity of new amide-substituted oxindole derivatives
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DOI: 10.1016/j.tet.2017.10.049
Abstract: Abstract Oxindole derivatives are of growing importance in organic synthesis and in the synthesis of biologically active compounds, therefore, a very important goal is to develop new ways of modifying such scaffold. In this article… read more here.
Keywords: amide substituted; oxindole derivatives; group; reactivity new ... See more keywords
Synthesis and Reactivity of Triangular Heterometallic Complexes Containing Zn-Zn Bond.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00956
Abstract: This work provides a facile access to a series of triangular [Zn2M] (M = group 10 and 11 metals) clusters. Treatment of Zn-Zn-bonded compounds [LZn-ZnL] (L = CH3C(2,6-iPr2C6H3N)CHC(CH3)(NCH2CH2PR2); R = Ph, iPr) with zero-valent transition-metal… read more here.
Keywords: heterometallic complexes; triangular heterometallic; reactivity triangular; synthesis reactivity ... See more keywords
Synthesis and Reactivity of Fe(II) Complexes Containing Cis Ammonia Ligands.
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DOI: 10.1021/acs.inorgchem.3c03757
Abstract: The development of earth-abundant transition-metal complexes for electrocatalytic ammonia oxidation is needed to facilitate a renewable energy economy. Important to this goal is a fundamental understanding of how ammonia binds to complexes as a function… read more here.
Keywords: synthesis reactivity; reactivity complexes; ammonia; cis ammonia ... See more keywords
Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00018
Abstract: Two methods for the synthesis of the bis(imidazolin-2-ylidene)carbazolide cobalt(I) complex [Co(bimcaHomo)] (2) have been developed. The first route relies on the direct transmetalation of the in s... read more here.
Keywords: cobalt; reactivity cobalt; cobalt iridium; iridium complexes ... See more keywords
Synthesis, Reactivity, and Insights into the Lewis Acidity of Mononuclear Titanocene Imido Complexes Bearing Sterically Demanding Terphenyl Moieties
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00452
Abstract: The titanocene imido complex 2 with a m-terphenyl moiety is synthesized by reacting Cp2Ti(η2-Me3SiC2SiMe3) (1) with m-terphenyl azide. Subsequent reactivity studies with tetrahydrofuran, pyridine, ... read more here.
Keywords: imido; insights lewis; reactivity insights; synthesis reactivity ... See more keywords
Synthesis and Reactivity of Metal–Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for β-Alkylation of Secondary Alcohols with Primary Alcohols
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DOI: 10.1021/acs.organomet.8b00432
Abstract: Three unsymmetrical NNN ligands with a 2-hydroxypyridyl fragment were used to react with RuHCl(PPh3)3(CO), affording the three bidentate ruthenium hydride complexes [(R1-C5H3N-CH2-C5H3N-C5H3N-R2)Ru... read more here.
Keywords: hydride complexes; ruthenium hydride; synthesis reactivity; reactivity metal ... See more keywords