Synthesis and redox activity of carbene-coordinated group 13 metal radicals.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00216g
Abstract: Carbenes are known to stabilize main group element compounds with unusual electronic properties. Herein, we report the synthesis of carbene-stabilized group 13 metal radicals (cAAC)MX2(IPr) (M = Al, X = Br 3; M = Ga,… read more here.
Keywords: metal radicals; synthesis redox; group; group metal ... See more keywords
Synthesis and redox characteristics of iron complexes with triphenylsubstituted corrols in the presence of argon and oxygen
Sign Up to like & getrecommendations! Published in 2017 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023617120051
Abstract: Abstractpara-Substituted iron meso-triphenylcorrole derivatives [Fe(ms-p-R-Ph)3Cor] containing electron- donating (R = OMе) and electron-drawing (R = NO2) groups in phenyl rings are synthesized and characterized by 1H NMR, electronic absorption spectroscopy, and mass spectrometry. The effect… read more here.
Keywords: oxygen; synthesis redox; redox characteristics; iron ... See more keywords
Synthesis, Redox and Spectroscopic Properties of Pterin of Molybdenum Cofactors
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27103324
Abstract: Pterins are bicyclic heterocycles that are found widely across Nature and are involved in a variety of biological functions. Notably, pterins are found at the core of molybdenum cofactor (Moco) containing enzymes in the molybdopterin… read more here.
Keywords: redox spectroscopic; properties pterin; synthesis redox; spectroscopic properties ... See more keywords