An alternative novel total synthesis of relgro.
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DOI: 10.1080/14786419.2025.2575122
Abstract: A novel stereoselective approach for synthesising a 10-membered β-resocylic macrolide, relgro (1) was established, utilising known chiral bis-epoxide and commercially made available Orsellinic acid. Key steps included Yamaguchi macrolactonization, hydroboration and alkylation of 1,3-dithiane as… read more here.
Keywords: total synthesis; synthesis relgro; alternative novel; relgro ... See more keywords