Articles with "synthesis stereochemical" as a keyword



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Synthesis, stereochemical and biological studies of some N-cyclohexylcarbamoyl -2,6-diarylpiperidin-4-ones

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Published in 2017 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2016.10.035

Abstract: Abstract A series of N -cyclohexylcarbamoylpiperidin-4-ones were synthesized by the addition reaction of corresponding piperidin-4-ones with cyclohexylisocyanate in benzene. The structure and stereochemistry of the synthesized N- cyclohexylcarbamoyl -2, 6-diarylpiperidin-4-ones, were established on the basis… read more here.

Keywords: cyclohexylcarbamoyl diarylpiperidin; diarylpiperidin ones; studies cyclohexylcarbamoyl; synthesis stereochemical ... See more keywords
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Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers.

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Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b07181

Abstract: A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism (VCD) technique… read more here.

Keywords: 12c 13c; synthesis stereochemical; stereochemical assignment; asymmetric synthesis ... See more keywords
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Synthesis and Stereochemical Characterization of a Novel Chiral α-Tetrazole Binaphthylazepine Organocatalyst

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27165113

Abstract: A novel α-tetrazole-substituted 1,1′-binaphthylazepine chiral catalyst has been synthesized and its absolute configuration has been determined by DFT computational analysis of the vibrational circular dichroism (VCD) spectrum of its precursor. The VCD analysis, carried out… read more here.

Keywords: characterization novel; synthesis stereochemical; novel chiral; stereochemical characterization ... See more keywords