Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04261
Abstract: Functionalized enantiopure organosilanes are important building blocks with applications in various fields of chemistry; nevertheless, asymmetric synthetic methods for their preparation are rare. Here we report the first organocatalytic enantioselective synthesis of tertiary silyl ethers… read more here.
Keywords: silyl ethers; synthesis stereogenic; organocatalytic asymmetric; asymmetric synthesis ... See more keywords
A Ni-catalyzed asymmetric C(sp)–P cross-coupling reaction for the synthesis of P-stereogenic alkynylphosphines
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DOI: 10.1039/d2sc05841c
Abstract: Due to the high reactivity of the triple bond, P-stereogenic alkynylphosphines could be easily derivatized, serving as universal building blocks for structurally diverse phosphine compounds. However, the synthesis of alkynylphosphines via direct P–C bond formation… read more here.
Keywords: cross coupling; reaction; synthesis stereogenic; catalyzed asymmetric ... See more keywords
Organocatalytic asymmetric synthesis of P-stereogenic molecules
Sign Up to like & getrecommendations! Published in 2023 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2023.1132025
Abstract: P-chirality broadly appears in natural and synthetic functional molecules. The catalytic synthesis of organophosphorus compounds bearing P-stereogenic centers is still challenging, due to the lack of efficient catalytic systems. This review summarizes the key achievements… read more here.
Keywords: synthesis stereogenic; stereogenic molecules; organocatalytic asymmetric; asymmetric synthesis ... See more keywords