Diene Salts of the Adamantane Series: Synthesis, Structure, and Chemical Transformations
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202300585
Abstract: Mono‐ and bis‐pyridinium, phosphonium and sulfonium allylic salts, containing adamantane fragment, have been obtained from the substitution reaction in 1,4‐dibromo‐2‐butene. It was found, that the attack of triethylamine undergoes from the sterically less hindered side,… read more here.
Keywords: diene salts; series synthesis; structure; synthesis structure ... See more keywords
Synthesis, structure and antiproliferative activity of organometallic iridium(III) complexes containing thiosemicarbazone ligands
Sign Up to like & getrecommendations! Published in 2017 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.3610
Abstract: A series of half-sandwich iridium complexes (1–4) with thiosemicarbazone ligands in two types of coordination modes were synthesized and characterized. The molecular structures of compounds 1, 2 and 3 were determined using single-crystal X-ray diffraction… read more here.
Keywords: iridium; thiosemicarbazone ligands; synthesis structure; structure antiproliferative ... See more keywords
(N),C,N-Coordinated Heavier Group 13-15 Compounds: Synthesis, Structure and Applications.
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DOI: 10.1002/cplu.202000620
Abstract: The aim of this review is to summarize recent achievements in the field of (N),C,N-coordinated group 13-15 compounds not only regarding their synthesis and structure, but mainly focusing on their potential applications. Relevant compounds contain… read more here.
Keywords: synthesis structure; group; coordinated heavier; group compounds ... See more keywords
Xanthones with multiple roles against diabetes: their synthesis, structure‐activity relationship, and mechanism studies
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DOI: 10.1002/ddr.22170
Abstract: A four‐step synthetic process has been developed to prepare 1,3,5,8‐tetrahydroxyxanthone (2a) and its isomer 1,3,7,8‐tetrahydroxyxanthone (2b). 25 more xanthones were also synthesized by a modified scheme. Xanthone 2a was identified as the most active inhibitor… read more here.
Keywords: multiple roles; diabetes synthesis; roles diabetes; synthesis structure ... See more keywords
Synthesis, Structure, and Properties of Dion–Jacobson Double‐Layered Perovskites A′SmNb2O7 (A′ = Rb, K, Na, Li, H)
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DOI: 10.1002/ejic.202400563
Abstract: Dion‐Jacobson‐type layered perovskite compounds A′SmNb2O7 (A′ = Rb, K, Na, Li, H) were synthesized using solid‐state and ion‐exchange methods. While the parent solid‐state product RbSmNb2O7, has previously been studied, the ion‐exchanged compounds were obtained and… read more here.
Keywords: spectroscopy; structure properties; synthesis structure; dion jacobson ... See more keywords
On the Synthesis, Structure and Reactivity of MesDPM Triel Dihydrides
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DOI: 10.1002/ejic.202500403
Abstract: Herein, the simple synthesis of triel dihydride complexes with the sterically demanding 1,5,9‐trimesityldipyrromethene (MesDPM) ligand is reported. With these compounds, reactivity studies are carried out, opening access to new classes of MesDPM triels. All compounds… read more here.
Keywords: structure reactivity; synthesis structure; reactivity mesdpm; synthesis ... See more keywords
Synthesis, Structure, and Fluorescence Behavior of Profluorescent 8-Amino BODIPY Nitroxides
Sign Up to like & getrecommendations! Published in 2019 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201801758
Abstract: Author(s): Schultz-Simonton, Wiley | Advisor(s): Braslau, Rebecca | Abstract: A series of novel 8-amino BODIPY profluorescent nitroxides and the corresponding N-ethoxyamine derivatives were synthesized with varying substitution and molecular geometries. Single crystal X-ray diffraction data… read more here.
Keywords: synthesis structure; bodipy nitroxides; amino bodipy; profluorescent ... See more keywords
Amine‐Substituted Diazocine Derivatives – Synthesis, Structure, and Photophysical Properties
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DOI: 10.1002/hlca.201800146
Abstract: 1 Amine-substituted Diazocine Derivatives – Synthesis, Structure and Photophysical Properties Mark A. Gregory, Bolong Zhang, b Andrew J. Tilley, b Tamika Scheerlinck, Jonathan M. White, and Wallace W. H. Wong* b a School of Chemistry,… read more here.
Keywords: amine substituted; diazocine derivatives; chemistry; derivatives synthesis ... See more keywords
Synthesis and structure-activity relationships of carbohydrazides and 1,3,4-oxadiazole derivatives bearing an imidazolidine moiety against the yellow fever and dengue vector, Aedes aegypti.
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DOI: 10.1002/ps.4722
Abstract: BACKGROUND 1,3,4-Oxadiazole and imidazolidine rings are important heterocyclic compounds exhibiting a variety of biological activities. In this study, novel compounds with oxadiazole and imidazolidine rings were synthesized from 3-(methylsulfonyl)-2-oxoimidazolidine-1-carbonyl chloride and screened for insecticidal activities.… read more here.
Keywords: per mosquito; aedes aegypti; activity; synthesis structure ... See more keywords
SYNTHESIS AND STRUCTURE OF ESTERIFICATION PRODUCTS OF 6-ARYL-1,2,3,6,7,7а-HEXAHYDRO-3а,6-EPOXYISOINDOLE-7-CARBOXYLIC ACIDS
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/4990
Abstract: Установлено, что взаимодействие 5-арилфурфуриламинов с малеиновым ангидридом приводит к образованию 6-арил-3а,6-эпоксиизоиндоло-7-карбоновых кислот (циклическая форма), которые в растворе при комнатной температуре находятся в динамическом равновесии с N -фурфурилмалеинамидами (открытая форма). При этерификации этих таутомерных смесей метанолом… read more here.
Keywords: hexahydro epoxyisoindole; aryl hexahydro; esterification products; products aryl ... See more keywords
SYNTHESIS, STRUCTURE, AND ANTIVIRAL PROPERTIES OF NOVEL 2-ADAMANTYL-5-ARYL-2 H -TETRAZOLES
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DOI: 10.1007/6073
Abstract: The reaction of 5-aryl- NH -tetrazoles with adamantan-1-ol in concentrated sulfuric acid proceeds regioselectively with the formation of the corresponding 2-adamantyl-5-aryl-2 H -tetrazoles. Nitration of these compounds leads to 2-(adamantan-1-yl)-5-(3-nitroaryl)-2 H -tetrazoles. The structures and… read more here.
Keywords: novel adamantyl; adamantyl aryl; spectroscopy; synthesis structure ... See more keywords