Palladium‐Catalyzed Aerobic Synthesis of Terminal Acetals from Vinylarenes Assisted by π‐Acceptor Ligands
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201601517
Abstract: Terminal acetals were synthesized from various vinylarenes and 1,2‐ or 1,3‐diols using a simple PdCl2(MeCN)2/methoxy‐p‐benzoquinone (MeOBQ)/CuCl catalyst system and 1 atm of O2 under mild reaction conditions by the anti‐Markovnikov nucleophilic attack of an oxygen nucleophile… read more here.
Keywords: aerobic synthesis; synthesis terminal; terminal acetals; palladium catalyzed ... See more keywords
Synthesis of Terminal Bis(hydrosulfido) and Disulfido Complexes of Ni(II) from a Geometrically Frustrated Tetrahedral Ni(II) Chloride Complex.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00787
Abstract: Recent studies have highlighted how reactive sulfur species (RSS) can be regulated and transported by metal-sulfur coordination compounds. We report herein the reactivity of PhB(tBuIm)3NiCl (1) with RSS, including the hydrosulfide anion ([Bu4N][SH]) and a… read more here.
Keywords: hydrosulfido disulfido; phb tbuim; terminal bis; synthesis terminal ... See more keywords