Synthesis of Trapen Ligand-Based U(IV) and Th(IV) 2-Phosphaethynolate Complexes and Comparison of Covalency with Corresponding Ti(IV) Analogues.
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DOI: 10.1021/acs.inorgchem.2c02263
Abstract: The involvement of the 2-phosphaethynolate anion species with ambident nucleophilic properties serves as an essential protocol for synthesizing oxygen-bound or phosphorus-bound complexes. This work mainly describes the synthesis and characterization of U, Th, and Ti… read more here.
Keywords: synthesis trapen; covalency; phosphaethynolate; phosphaethynolate complexes ... See more keywords