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Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2021.09.032
Abstract: ABSTRACT A catalytic asymmetric total synthesis of (+)-vincamine is presented. Key features of the synthesis include a Pd-catalyzed enantioselective decarboxylative allylation to form the C20 quaternary stereogenic center and a stereoselective iminium reduction to install…
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Keywords:
total synthesis;
synthesis vincamine;
enantioselective total;